耐高温低碳烃无水压裂液室内研究

Experimental Research on Performances of Hydrocarbon-Based Heat-Resistance Low-Carbon Fracturing Fluid

王满学 何静 王永炜

WANG Manxue HE Jing WANG Yongwei

西安石油大学化学化工学院, 陕西西安 710065; 陕西延长石油(集团)有限责任公司研究院, 陕西西安 710075

College of Chermistry & Chemical Engineering, Xi’an Shiyou University, Xi’an, Shaanxi, 710065, China; Research Institute of Exploration and Development, Yanchang Oilfield Company, Xi’an, Shaanxi, 710075, China

针对目前国内低碳烃无水压裂液耐温能力差的问题，用戊烷、磷酸酯胶凝剂LPEA-1和黏度促进剂FS-1配制了耐高温低碳链烃无水压裂液（戊烷基Frac-H压裂液），并对其性能进行了初步评价。通过室内试验研究，确定戊烷基Frac-H压裂液的基本配方为95.8%戊烷+2.0% LPEA-1+2.2% FS-1，按此配制的压裂液在180 s后黏度达到最大；在温度为130℃、剪切速率为170 s-1条件下连续剪切120 min后的黏度大于50 mPa·s；破胶时不需加入破胶剂，且破胶液无残渣；戊烷基Frac-H压裂液对页岩储层的伤害稍大于致密性储层，但显著低于水基压裂液对页岩岩心的伤害。研究结果表明，用戊烷、磷酸酯和黏度促进剂配制的戊烷基Frac-H压裂液，可以满足非常规储层高温油气井压裂施工对压裂液性能的要求。

Conventional water-free fracturing fluid can characterized by poor heat-resistance.Under such circumstances,water-free fracturing fluids based on low-carbon chain hydrocarbon pentane,phosphate surfactant (LPEA-1) and viscosity promoter (FS-1) were developed with desirable heat-resistant performances.In the concerned study,the properties of the fracturing fluid Frac-H were evaluated.The viscosity of the fracturing fluids is higher than 50 mPa·s after a continuous shearing of 120 min under temperature 130℃ and a shearing rate of 170 s-1 and it may have maximum viscosity after 180 s.No gel breaker is required during gel breaking processes.In addition,no residue was found in the fluids after gel breaking.The pentane-based Frac-H fracturing fluid may cause slightly higher damage to shale formations than to tight formations,but they are much less than those induced by water-based fracturing fluids.Research results showed that the pentane-based Frac-H fracturing fluid with pentane,phosphate surfactant and viscosity promoter can effectively meet the performance requirements towards frac fluid in unconventional reservoirs fracturing treatment.

https://doi.org/10.11911/syztjs.201704016