含次生生物成因煤层气的碳同位素组成特征——以淮南煤田为例

CHARACTERISTICS OF CARBON ISOTOPE COMPOSITION FROM SECONDARY BIOGENIC GAS IN COALBED GASES--TAKING THE HUAINAN COAL FIELD AS AN EXAMPLE

张小军 陶明信 马锦龙 王万春 孙国强

Zhang Xiaojun Tao Mingxin Ma Jinlong Wang Wanchun Sun Guoqiang

中国石油勘探开发研究院, 西北分院, 兰州, 730020 2. 中国科学院, 地质与地球物理研究所, 气体地球化学重点实验室, 兰州, 730000 3. 北京师范大学, 资源学院, 北京, 100875 4. 兰州大学, 资源环境学院, 兰州, 730000

Northwest Branch, Research Institute of Petroleum Exploration and Development, Petro China, Lanzhou, Gansu 730020, China 2. Key Laboratory of Gas Geochemistry, Institute of Geology and Geophysics, Chinese Academy of Sciences, Lanzhou, Gansu 730000, China 3. College of Resources Sciences and Technology, Beijing Normal University, Beijing 100875, China 4. School of Resources and Environmental Sciences, Lanzhou University, Lanzhou, Gansu 730000, China

淮南煤田煤层气属于热成因和次生生物成因气的混合气。不同矿区和不同煤层中煤层气的δ13C1值有明显的不同,这主要是由于现今淮南煤田的煤层气藏中后期生成的次生生物气与残留在煤层中的热解气混合比例不同造成的。研究显示,淮南煤田煤层气的δ13C1值明显轻于我国热成因煤型气和世界主要地区煤层气的δ13C1值,表现出了含次生生物成因煤层气的δ13C1值的变化特征;而δ13C2值明显与我国热成因煤型气和世界主要地区煤层气的δ13C2值处于同一分布范围,表现出了热成因气δ13C2值的特征。淮南煤田煤层气的δ13CCO2值反映出煤层气中的CO2主要为煤热解而来,部分是次生生物气生成过程中,经过了微生物的还原作用而残留的CO2。

Coalbed gases in Huainan coal field is a gas mixture resulted from thermogenic methane and secondary biogenic gas.And the δ13C1 value of coalbed gases is very different among different mines and coal beds.This is mainly because the difference of mixing proportion between the remaining pyrolysis gas from coalbed and the secondary biogenic gas from post-stage in Huainan coal field.Compared with Chinese thermogenic coalbed gases and others from the world's major regions by δ13C1 and δ13C2 values,it is showed that the δ13C1 value from Huainan coal field is much smaller.The variational property of δ13C1 value is characterized by containing secondary biogenic gas.However,the distribution of δ13C2 value in Huainan coal field is obviously in same position with the one that from Chinese thermogenic coalbed gases and the world's major regions,and it is characterized by property of thermogenic methane.And from the δ13CCO2 value of coalbed gases,we can inferred that CO2 in methane is mainly resulted from coal pyrolysis,and part of it is the remaining CO2 from microbial reduction occurring in the secondary biogenic gas generating process.

国家重点基础研究发展计划(973计划)项目(2002CB211701);国家自然科学基金项目(40372065)共同资助

https://doi.org/10.11781/sysydz200906622