少量/微量烃类气体的收集、定量分析及碳同位素分析方法

2003年 25卷 第5期
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COLLECTION, QUANTITATIVE ANALYSIS AND CARBON ISOTOPIC ANALYSIS METHODS OF MINOR/TRACE HYDROCARBON GASES
刘金钟 向同寿
LIU Jin-zhong XIANG Tong-shou
中国科学院, 广州地球化学研究所, 有机地球化学国家重点实验室, 广东, 广州, 510640
State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510640, China
在生烃动力学的研究中,需要对热模拟产生的少量或微量的烃类气体进行定性、定量分析及单体烃碳同位素分析。金管中的气体经托普勒汞泵收集定量后送入气相色谱仪进行成分分析,剩余的气体经收集、转移后进行碳同位素分析。文中介绍了系统的详细结构、工作原理,并讨论了影响分析精度的几个因素。
In the study of hydrocarbon-generation dynamics, it is needed to make quantitative analysis, qualitative anakysis and simple-hydrocarbon carbon-isotopic analysis on minor or trace hydrocarbon gases generated from thermal simulation.The gases in gold tubes were collected and quantified by a Toepler mercury pump, and then were sent into a gas chromatogaph to make compositional analysis.The residual gases were collected and transferred so as to make carbon isotopic analysis.In this paper, the detailed structure and operating mechanism of the system were introduced, and several factors affecting analysis precision were discussed.
烃; 碳同位素; 气相色谱; 气体分析;
hydrocarbon; carbon isotope; gas chromatography; gas analysis;
国家自然科学基金(49972040)
https://doi.org/10.11781/sysydz200305492