论文详情
饱和烃和芳烃的高压液相色谱法精细分离
石油实验地质
2003年 25卷 第2期
阅读：137
查看详情
Title
FINE SEPARATION OF SATURATED HYDROCARBON AND AROMATIC HYDROCARBON BY HIGH PERFORMANCE LIQUID CHROMATOGRAPHY
Authors
WANG Hui-tong
YOU Jian-chang
WANG Pei-rong
ZHANG Da-jiang
单位
中国石油勘探开发科学研究院 油气地球化学重点实验室, 北京 100083
Organization
The Key Laboratory Petrolemum Geochemistry, CNPC, Beijing 100083, China
摘要
该文介绍了用高压液相色谱对族组分中的饱和烃、单环芳烃、二环芳烃及三环以上芳烃的精细分离方法。用二级活度的氧化铝除去非烃和沥青质,用正己烷和二氯甲烷依次淋洗出(硅胶)色谱柱上的饱和烃、单环芳烃、二环芳烃及三环以上芳烃。该方法同国外方法相比具有快速、节省试剂的优点,色质谱图显示各组分有较高的分离度。
Abstract
A method to finely separate saturated hydrocarbon and aromatic hydrocarbon by high performance liquid chromatography(HPLC)was introduced.The oil or bitumen samples were pre prepared by being put in a alumina column,saturated hydrocarbon and aromatic hydrocarbon were eluted together from the column using 90:10 of hexane:ether.After concentrated,the saturated hydrocarbon and aromatic hydrocarbon were ready for further separation by HPLC with the eluent hexane and dichloromethane.The fraction of saturates,monoaromatics,diaromatics and triaromatics would be collected under the control of UV detector and fraction collector.Compared with the method from abroad,the advantages of our method are visible:reagent and time saving.
关键词：
高压液相色谱;
饱和烃;
单环芳烃;
二环芳烃;
三环芳烃;
分离;
Keywords:
high performance liquid chromatography;
saturated hydrocarbon;
monoaromatic hydrocarbon;
diaromatic hydrocarbon;
triaromatic hydrocarbon;
separation;
DOI
https://doi.org/10.11781/sysydz200302221
论文详情