论文详情
适用于含聚回注水的疏水缔合聚合物的综合性能*
油田化学
2020年 37卷 第1期
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Title
Comprehensive Performance Evaluation of Associated Polymers Suitable for Reinjection Water Containing Polymer
Authors
QUE Tingli,GUAN Dan,JIAO Qiuju,PATIGULI·Maimaiti
摘要
新疆油田化学驱采用高矿化度含聚回注水作为注入水。研究了含聚回注水配制的普通聚合物HPAM和疏水缔合聚合物KYPAM的増黏性、流变性、黏弹性、长期稳定性、不可及孔隙体积(IPV)和驱油性能。研究结果表明:KYPAM 具有特殊的空间网状结构,在含聚污水中具有更好的增黏性、流变性、黏弹性;在含聚回注水中KYPAM 的抗老化能力好于 HPAM,经过 90 d 的老化后,质量浓度 1500 mg/L 的 KYPAM 溶液的黏度保留率为81.4%,而HPAM溶液的只有40.2%;在渗透率150×10-3 μm2左右岩心中,质量浓度为1500 mg/L的 KYPAM溶液的IPV为19.6%,而HPAM溶液的IPV为22.1%,KYPAM启动相对小孔喉的能力比HPAM高;在渗透率150×10-3 μm2左右的人造砾岩岩心中,水驱后注入0.5 PV的浓度为1200、1500 mg/L的聚合物溶液,KYPAM的驱油效率比HPAM的高2%~3%。图11表5参19
Abstract
High salinity polymer-bearing reinjection water is used as injection water for chemical flooding in Xinjiang oilfield. The comprehensive performance of HPAM and hydrophobic associating polymer KYPAM prepared with polymer-containing reinjection water,including viscosity,rheology,viscoelasticity,long-term stability,inaccessible pore volume(IPV)and oil displacement performance,were evaluated. The results showed that KYPAM had better viscous,rheological and viscoelastic properties due to its special network structure. The anti-aging ability of KYPAM was better than that of HPAM. After aging for 90 days,the viscosity retention rate of KYPAM solution with the concentration of 1500 mg/L was 81.4%,while that of HPAM solution was only 40.2%. In the core permeability of 150×10-3 μm2,the IPV of 1500 mg/L KYPAM solution was 19.6%,while the IPV of HPAM solution was 22.1%. Compared with HPAM,KYPAM had a higher ability of starting relative pore-throat. In the core permeability of 150× 10-3 μm2,when 0.5 PV of polymer solution with the concentration of 1200—1500 mg/L was injected after water flooding,the oil displacement efficiency of KYPAM solution was 2%—3% higher than that of HPAM solution.
关键词:
疏水缔合聚合物;
含聚回注水;
黏度;
长期稳定性;
驱油效率;
Keywords:
hydrophobic associative polymer;
reinjection water containing polymer;
viscosity;
long-term stability;
volumetric sweep efficiency;
DOI
10.19346/j.cnki.1000-4092.2020.01.019