矿化度对AM/AMPS类就地聚合堵剂性能的影响

2015年 22卷 第01期
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Effect of salinity on performance of AM/AMPS in-situ polymerization plugging agent
蒲万芬 杨再广 丁黎
西南石油大学石油与天然气工程学院,四川 成都 610500 西南石油大学油气藏地质及开发国家重点实验室,四川 成都 610500 中国石化胜利油田分公司新春采油厂,山东 东营 257000)
Organization
School of Petroleum and Natural Gas Engineering, Southwest Petroleum University, Chengdu 610500, China State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Engineering, Southwest Petroleum University, Chengdu 610500, China Xinchun Oil Production Plant, Shengli Oilfield Company, SINOPEC, Dongying 257000, China)
摘要
就地聚合堵剂由于具备良好的注入性、成胶时间可控及成胶强度大等优点受到了广泛关注,而针对高温高盐油藏的就地聚合堵剂的成胶时间和稳定性还需进一步优化。实验研究了不同矿化度对体系成胶性能的影响,并对比了Na+,Ca2+,Mg2+这3种阳离子的影响程度。结果表明:3种阳离子对胶体稳定性影响由大到小依次为Ca2+,Mg2+,Na+;Na+对成胶时间影响最大,对胶体稳定性影响最小,可使凝胶堵剂保持较长时间不脱水;随着各离子质量浓度的不断增加,胶体稳定性降低。
Abstract
In-situ polymerization plugging agent has been widely concerned due to the advantages of good injection property, controllable gelation time and strong gel strength. However, the gelation time and stability of high temperature and high salinity reservoirs need to be further improved. In this paper, the effects of different salinity types on the gelation performance have been researched experimentally and the infuence degree of Na+, Ca2+ and Mg2+ is compared. The results show that some cations in the formation water, to some extent, play a positive role in promoting the gelation time and gelation strength of system. The order of their effects on system gelation is as follows: Ca2+>Mg2+>Na+. Na+ has the greatest effect on the gelation time of plugging agent and has the minimum impact on the stability of colloid, which can keep the gel plugging agent from syneresis for a long time. As the concentration of each ion increases, the stability of colloid decreases.
关键词:
就地聚合; 凝胶; 堵剂; 高温高盐油藏; 离子;
Keywords:
in-situ polymerization; gel; plugging agent; high temperature and high salinity reservoir; ion;
基金项目
DOI
10.6056/dkyqt201501022