多孔介质中气- 液- 吸附三相相平衡计算

2004年 11卷 第03期
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The Phase Equilibrium Calculation of Gas-Liquid-Adsorption Three Phases in the Porous Media


张茂林 梅海燕 郭 平 杜志敏 孙良田
Zhang Maolin ,Mei Haiyan,Guo Ping,et al.


西南石油学院石油工程学院,成都
在提出多孔介质中气相、液相与吸附相的三相相平衡假设条件之后,应用空穴溶液气体吸附FHVSM模型建立了气相、液相与吸附相之间的三相相平衡计算热力学模型。在等容衰竭试验模拟计算中,分别研究了有多孔介质和无多孔介质、考虑毛细管压力和不考虑毛细管压力、以及考虑吸附现象作用和不考虑吸附现象作用时,地层流体高压物性参数的变化和差异,并得出研究结论。在对研究所得结论的合理性进行解释之后,给出了一个指导制定凝析气藏开发方式的重要技术性要点。
Following presenting the hypothesis of the gas , liquid and
adsorption three phases equilibrium in the porous media , the
phase equilibrium calculation thermodynamic model of gas ,liquid
and adsorption three phases is set up in this paper by using the
Flory Hugging vacancy solution model of gas adsorption. In
simulating the constant volume depletion experiment ,the variety
and difference of high pressure physical parameters are
investigated and the research conclusion is educed respectively
for existing or non-existing the porous media ,considering or non-
considering the capillary pressure , and being or non-being the
adsorption phenomena action. After interpreting the rationality of
the research conclusion , an important technology point for
instructing the exploitation mode of the gas condensate reservoir is
presented in the end of this paper.


多孔介质 吸附 三相相平衡 等容衰竭 毛细管压力 凝析气藏;
Porous media , Adsorption , Three phases equilibrium, Constant volume depletion , Capillary pressure , Gas condensate reservoir.


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