论文详情

钻井液处理剂璜化高分子化合物降解放出H2S的途径研究

石油钻采工艺

1999年 21卷第5期

阅读：71

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Title

STUDY ON THE APPROACH OF H2S RELEASED FROM DEGRADED SULFONATED POLYMER OF DRILLING MUD CONDITIONING AGENT

作者

郭生武陈志昕韩勇

Authors

Guo Shengwu Chen Zhixin Han Yong

单位

中国石油天然气集团公司石油管材研究所

摘要

在高温或SRB或电解作用下,对水基钻井液中的处理剂磺化高分子化合物进行降解反应,试验证实分别释放出了H2S,在室温下腐蚀产物为Fe9S8,在60℃以上为FeS,这种来源的H2S同样是有害的,可能造成油井管的腐蚀并使钻井液性能变差。

Abstract

At high temperature or SRB or electrolytic action,the sulfonated high molecular compound of water-based drilling mud conditioning agent is degraded releasing out H2S.The corrosion products are Fe9S8 at room temperature,and FeS when temperature is above 60℃.The derived H2S is also hazardous to the drilling string and casing,and may reduce the performance of drilling mud.

关键词：

磺化; 聚合物; 降解; 硫化氢腐蚀; 金属; 钻井液;

Keywords:

sulfurization; polymer; degradation; hydrogen sulfide; corrosion;

基金项目

DOI

10.3969/j.issn.1000-7393.1999.05.010