多金属氧簇有机⁃无机杂化及其固载化研究进展

Progress in Research on Polyoxometalates Organic⁃Inorganic Hybridization and Immobilization

崔亚男 郭子谊 赵琳 李远哲 黄现强

Ya'nan Cui Ziyi Guo Lin Zhao Yuanzhe Li Xianqiang Huang

山东省化学储能与新型电池技术重点实验室/聊城大学 化学化工学院，山东 聊城 252000

Shandong Key Laboratory of Chemical Energy Storage and New Cell Technology/School of Chemistry & Chemical Engineering，Liaocheng University，Liaocheng Shandong 252000，China

多金属氧簇（POMs）是一类由最高氧化态的前过渡金属（Mo、W、V、Nb和Ta）组成的分子基金属氧化物。纯无机POMs在极性溶剂中的高溶解度和低比表面积限制了其实际应用。有机?无机POMs和固载化POMs复合材料在催化、能量转换、储能和磁性等方面的应用前景引起了人们的广泛关注。对过渡金属/镧系元素修饰的有机?无机POMs和固载化POMs复合材料的设计合成进行了综述，并对POMs有机?无机杂化及其固载化进行了总结和展望。

Polyoxometalates (POMs) are molecular metal oxides composed of transition metals in their highes oxidation states (Mo,W,V,Nb,Ta). The high solubility and low specific surface area of pure inorganic POMs limi its practical applications in polar solvents. Due to the widespread applications of organic?inorganic hybrid POMs and immobilized POMs in the field of catalysis, energy conversion, storage and magnetism have attracted considerable attention.The design and synthesis of transition metal/Lanthanide modified organic?inorganic polyoxometalates and immobilized polyoxometalates composites are reviewed,and the practical applications of POMs with novel structures are summarized and outlooked.

国家自然科学基金面上项目(21871125);国家自然科学青年基金项目(21401094);山东省自然科学基金面上项目(ZR2019MB043);山东省科技发展计划项目(2010GGX10304);聊城市科技发展计划项目(2014GJH01)

10.12422/j.issn.1672-6952.2023.04.006