钼酸盐基钙钛矿作为固体氧化物燃料电池阳极材料的研究进展

Progress of Molybdate⁃Based Perovskites as Anode Materials for Solid Oxide Fuel Cells

杨淯夫 李江馨 王鹏程 滕元魁 金芳军

Yufu Yang Jiangxin Li Pengcheng Wang Yuankui Teng Fangjun Jin

长春理工大学 物理学院，吉林 长春 130022 中国矿业大学 材料与物理学院，江苏 徐州 221116

College of Physics，Changchun University of Science and Technology，Changchun Jilin 130022，China School of Materials Science and Physics，China University of Mining and Technology，Xuzhou Jiangsu 221116，China

固体氧化物燃料电池(SOFC)作为一种能量转换装置，因其清洁高效的工作方式，受到了社会各界的广泛关注和重视。阳极是SOFC的重要组成部分，寻找具有良好燃料催化活性的阳极材料是SOFC领域材料研究的重点工作。近年来，钼酸盐基钙钛矿材料作为SOFC阳极，在中低温区显示了优异的电导率和电化学性能，受到了国内外众多课题组的广泛关注。综述了钼酸盐基钙钛矿作为SOFC阳极的研究进展，从理论和实验的角度总结了不同掺杂情况对材料性能的影响，为今后材料的相关研究提供指导性的意见。

Solid oxide fuel cells (SOFC) as one of the energy conversion devices, have received widespread attention and importance from all walks of life because of its clean and efficient operation. Anode is an important part of SOFC. It is important to find anode materials with good fuel catalytic activity in SOFC field. In recent years, molybdat?based perovskite materials as SOFC anodes show excellent conductivity and electrochemical properties at low and medium temperatures, and have been extensively studied by many research groups. In this paper, the research progress of molybdate?base perovskite as SOFC anode is reviewed, and the effects of different doping conditions on the properties of materials are summarized from the theoretical and experimental results, so as to provide guidance for the future research of materials.

吉林省科技发展计划项目(20200201060JC);长春市科技局“青年科技人才创新创业专项”(21QC02)

10.12422/j.issn.1672-6952.2023.01.004